University of Cincinnati researchers show for the first time that they can connect an increase in electrical (ionic) conductivity with flexibility of their networks. The same team of researchers discovered intermediate phases seven years ago in amorphous or disordered materials where networks are covalently bonded.
The team's results are presented in "Fast-ion conduction and flexibility of glassy networks," to be published this spring in Physical Review Letters.
"We find that when networks become flexible their electrical conductivity increases precipitously," says Deassy Novita. "Now we will be able to chemically tune these materials for specific applications. For example, the batteries implanted in patients who have heart pacemakers make use of a solid electrolyte."
Novita is a third-year doctoral student working in the lab of Punit Boolchand, professor of electrical engineering in the University of Cincinnati's College of Engineering. Originally from Indonesia and now a U.S. citizen, Novita began the ground-breaking research as part of her doctoral thesis.
"This system has been studied by about 35 groups all over the world over the past two decades. We are the first to make these samples in a 'dry' state," says Boolchand. "Most people who studied these materials produced them unwittingly in the laboratory ambient environment where the relative humidity is typically 50%, and that leads to samples that are so to speak in a 'wet' state. By special handling of the materials, we were able to produce them in a dry state, where we can see the intrinsic behavior of these materials."
The intrinsic behavior shows samples to exist in three elastic domains. In the first domain, at low AgI (silver iodide) content (less than 9.5%) they form networks that are rigid but stressed. In the second domain, called the "intermediate phase," at a slightly higher content of AgI (9.5 to 37.8%), they form networks that are rigid but
Contact: Wendy Beckman
University of Cincinnati